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1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate, Thermo Scientific Chemicals
$81.53 - $226.64
Chemical Identifiers
| CAS | 68957-94-8 |
|---|---|
| Molecular Formula | C9H21O6P3 |
| MDL Number | MFCD00006583 |
| InChI Key | PAQZWJGSJMLPMG-UHFFFAOYSA-N |
| PubChem CID | 111923 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL1191109
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Thermo Scientific Chemicals
L1191109 |
10 g |
Each for $81.53
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AAL1191118
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Thermo Scientific Chemicals
L1191118 |
50 g |
Each for $226.64
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Description
1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.
Solubility
Miscible with dichloromethane, dimethyl formamide, dioxane, terahydrofuran, polar and aprotic organic solvents.
Notes
Moisture sensitive. Incompatible withstrong oxidizing agents.
Chemical Identifiers
| 68957-94-8 | |
| MFCD00006583 | |
| 111923 |
| C9H21O6P3 | |
| PAQZWJGSJMLPMG-UHFFFAOYSA-N |
Specifications
| 68957-94-8 | |
| 77°C | |
| C9H21O6P3 | |
| MFCD00006583 | |
| UN2924 | |
| Moisture sensitive | |
| Miscible with dichloromethane,dimethyl formamide,dioxane,terahydrofuran,polar and aprotic organic solvents. | |
| CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC | |
| 318.182 | |
| 318.19 | |
| 1-Propylphosphonic acid cyclic anhydride |
| 1.08 | |
| −3°C (26°F) | |
| 1.419 | |
| 10 g | |
| 5079255 | |
| 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, propane phosphonic acid anhydride, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene | |
| PAQZWJGSJMLPMG-UHFFFAOYSA-N | |
| 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide | |
| 111923 | |
| ≥50% soln. in ethyl acetate |
Safety and Handling
GHS H Statement
H225-H314-H336
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H225-H314-H335-H336
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber : 422-210-5
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only