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3-Bromo-1-trimethylsilyl-1-propyne, 98%
CAS: 38002-45-8 | C6H11BrSi | 191.143 g/mol
$190.66 - $695.53
Identifiants chimiques
| CAS | 38002-45-8 |
|---|---|
| Molecular Formula | C6H11BrSi |
| Molecular Weight (g/mol) | 191.143 |
| MDL Number | MFCD00134460 |
| InChI Key | GAPRPFRDVCCCHR-UHFFFAOYSA-N |
| Synonym | 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r |
| PubChem CID | 642589 |
| IUPAC Name | 3-bromoprop-1-ynyl(trimethyl)silane |
| SMILES | C[Si](C)(C)C#CCBr |
| Numéro de catalogue | Numéro du manufacturier. | Quantity | Prix | Quantité | |||||
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| Numéro de catalogue | Numéro du manufacturier. | Quantity | Prix | Quantité | |||||
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AAH5345106
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Thermo Scientific Chemicals
H5345106 |
5 g |
chaque for $190.66
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Connectez-vous ou enregistrez-vous pour vérifier votre prix et la disponibilité.
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AAH5345114
|
Thermo Scientific Chemicals
H5345114 |
25 g |
chaque for $695.53
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Connectez-vous ou enregistrez-vous pour vérifier votre prix et la disponibilité.
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Description
3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.
Solubility
Immiscible with water.
Notes
Store in cool place. Incompatible with strong oxidizing agents.
Identifiants chimiques
| 38002-45-8 | |
| 191.143 | |
| GAPRPFRDVCCCHR-UHFFFAOYSA-N | |
| 642589 | |
| C[Si](C)(C)C#CCBr |
| C6H11BrSi | |
| MFCD00134460 | |
| 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r | |
| 3-bromoprop-1-ynyl(trimethyl)silane |
Spécifications
| 44°C to 45°C (2mmHg) | |
| 5 g | |
| BrCH2C≡CSi(CH3)3 | |
| 2037650 | |
| 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r | |
| GAPRPFRDVCCCHR-UHFFFAOYSA-N | |
| 3-bromoprop-1-ynyl(trimethyl)silane | |
| 642589 | |
| 98% | |
| 1.17 |
| 38002-45-8 | |
| C6H11BrSi | |
| MFCD00134460 | |
| 63°C (145°F) | |
| Immiscible with water. | |
| C[Si](C)(C)C#CCBr | |
| 191.143 | |
| 191.14 | |
| 1.483 | |
| 3-Bromo-1-trimethylsilyl-1-propyne |
Sécurité et manipulation
GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.
P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H227-H315-H319-H335
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only