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Thermo Scientific Chemicals Burgess Reagent, 96%

Supplier:  Thermo Scientific Chemicals L2015503

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Catalog No. AAL2015503


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Description

Description

Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

Solubility
Soluble in organic solvents.

Notes
Store in cool place. Moisture sensitive. Incompatible with strong oxidizing agents.
Specifications

Specifications

Burgess Reagent
72°C to 82°C
MFCD00077815
1432131
methoxycarbonylsulfamoyl triethylammonium hydroxide, burgess reagent, carbomethoxysulfamoyltriethylammonium hydroxide, methoxycarbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulphamoyltriethylammonium hydroxide, methoxy-carbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulfa-moyl-triethylammonium hydroxide, methoxycarbonylsulphamoyl-triethylammonium hydroxide
YSHOWEKUVWPFNR-UHFFFAOYSA-N
(methoxycarbonyl)[(triethylazaniumyl)sulfonyl]azanide
11032497
96%
29684-56-8
C8H18N2O4S
1 g
Moisture sensitive
Soluble in organic solvents.
CC[N+](CC)(CC)S(=O)(=O)[N-]C(=O)OC
238.30
238.3

Chemical Identifiers

29684-56-8
238.30
YSHOWEKUVWPFNR-UHFFFAOYSA-N
11032497
C8H18N2O4S
MFCD00077815
methoxycarbonylsulfamoyl triethylammonium hydroxide, burgess reagent, carbomethoxysulfamoyltriethylammonium hydroxide, methoxycarbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulphamoyltriethylammonium hydroxide, methoxy-carbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulfa-moyl-triethylammonium hydroxide, methoxycarbonylsulphamoyl-triethylammonium hydroxide
CC[N+](CC)(CC)S(=O)(=O)[N-]C(=O)OC
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

TSCA : No

Recommended Storage : Store at -20°C

SDS
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RUO – Research Use Only