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Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II), Thermo Scientific Chemicals
$208.18 - $3871.49
Chemical Identifiers
| CAS | 16971-33-8 |
|---|---|
| Molecular Formula | C55H46ClOP3Ru |
| Molecular Weight (g/mol) | 952.41 |
| MDL Number | MFCD00049804 |
| InChI Key | IMPHYUNMDWWJAH-UHFFFAOYSA-M |
| Synonym | carbonylchlorohydridotris triphenylphosphine-ruthenium ii |
| PubChem CID | 71463878 |
| IUPAC Name | formaldehyde;hydride;ruthenium(2+);triphenylphosphane;chloride |
| SMILES | Cl[RuH++].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AA4495503
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Thermo Scientific Chemicals
04495503 |
1 g |
Each for $208.18
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AA4495506
|
Thermo Scientific Chemicals
04495506 |
5 g |
Each for $792.56
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AA4495514
|
Thermo Scientific Chemicals
04495514 |
25 g |
Each for $3,871.49
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Description
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 16971-33-8 | |
| 952.41 | |
| IMPHYUNMDWWJAH-UHFFFAOYSA-M | |
| 71463878 | |
| Cl[RuH++].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
| C55H46ClOP3Ru | |
| MFCD00049804 | |
| carbonylchlorohydridotris triphenylphosphine-ruthenium ii | |
| formaldehyde;hydride;ruthenium(2+);triphenylphosphane;chloride |
Specifications
| 16971-33-8 | |
| Gray | |
| [(C6H5)3P]3Ru(CO)(Cl)H | |
| 1 g | |
| carbonylchlorohydridotris triphenylphosphine-ruthenium ii | |
| IMPHYUNMDWWJAH-UHFFFAOYSA-M | |
| formaldehyde;hydride;ruthenium(2+);triphenylphosphane;chloride | |
| 71463878 | |
| Crystalline |
| 204°C to 206°C (decomposition) | |
| C55H46ClOP3Ru | |
| MFCD00049804 | |
| Light sensitive; Very Hygroscopic | |
| Insoluble in water,ethanol,and DMSO. Sparingly soluble in benzene,chloroform and acetone. | |
| Cl[RuH++].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 952.41 | |
| 952.41 | |
| Carbonylchlorohydridotris (triphenylphosphine)ruthenium (II) |
Safety and Handling
GHS H Statement
H302-H315-H319-H335
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
H302+H312+H332-H315-H319-H335
EINECSNumber : 241-051-0
TSCA : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only