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Cerium(III) chloride heptahydrate, 99%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1294718

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Catalog No. AAA1294718


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Description

Description

Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

Solubility
Soluble in alcohol and acetone. Slightly soluble in tetrahydrofuran. Insoluble in cold water.

Notes
Air sensitive. Hygroscopic. Incompatible with strong acids and strong oxidizing agents.
Specifications

Specifications

Cerium(III) chloride heptahydrate
50 g
MFCD00149634
Cerous chloride heptahydrate
372.60 (246.48 Anhydrous)
Odorless
18618-55-8
CeCl3·7H2O
14,1997
Soluble in alcohol,water,and acetone. Slightly soluble in tetrahydrofuran.
99%
Air sensitive; Hygroscopic

Chemical Identifiers

18618-55-8
CeCl3·7H2O
MFCD00149634
Cerous chloride heptahydrate
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314

DOTInformation : Hazard Class: 8; Packaging Group: II

EINECSNumber : 606-073-0

RTECSNumber : FK5100000

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

SDS
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