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o-Phenylenediamine, 98%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A119460I
Description
o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applicationso-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.
Solubility
Soluble in alcohol, chloroform, ether, slightly soluble in water. Soluble in hot water.
Notes
Moisture and air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
Specifications
o-Phenylenediamine | |
100°C to 103°C | |
256°C to 258°C | |
98% | |
MFCD00007721 | |
UN1673 | |
Air Sensitive | |
o-phenylenediamine, 1,2-phenylenediamine, 1,2-benzenediamine, 1,2-diaminobenzene, 2-aminoaniline, o-diaminobenzene, orthamine, o-benzenediamine, opda, ortho-phenylenediamine | |
GEYOCULIXLDCMW-UHFFFAOYSA-N | |
benzene-1,2-diamine | |
7243 | |
108.14 |
95-54-5 | |
1.27 | |
136°C (277°F) | |
C6H8N2 | |
5000 g | |
606074 | |
14,7284 | |
Soluble in alcohol,chloroform,ether,slightly soluble in water; Soluble in hot water. | |
C1=CC=C(C(=C1)N)N | |
108.144 | |
CHEBI:34043 | |
98% |
Chemical Identifiers
95-54-5 | |
108.144 | |
GEYOCULIXLDCMW-UHFFFAOYSA-N | |
7243 | |
benzene-1,2-diamine |
C6H8N2 | |
MFCD00007721 | |
o-phenylenediamine, 1,2-phenylenediamine, 1,2-benzenediamine, 1,2-diaminobenzene, 2-aminoaniline, o-diaminobenzene, orthamine, o-benzenediamine, opda, ortho-phenylenediamine | |
CHEBI:34043 | |
C1=CC=C(C(=C1)N)N |
Safety and Handling
GHS H Statement
H301-H341-H351-H312-H332-H319-H317
Toxic if swallowed.
Suspected of causing genetic defects.
Suspected of causing cancer.
Harmful in contact with skin.
Harmful if inhaled.
Causes serious eye irritation.
May cause an allergic skin reaction.
P201-P202-P261-P264b-P270-P271-P272-P280-P281-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P312-P330-P333+P313-P363-P501c
H301-H312+H332-H317-H319-H341-H351-H500
DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: PHENYLENEDIAMINES
EINECSNumber : 202-430-6
RTECSNumber : SS7875000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only