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o-Phenylenediamine, 98%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1194614

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Catalog No. AAA1194614


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Description

Description

o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.

Solubility
Soluble in alcohol, chloroform, ether, slightly soluble in water. Soluble in hot water.

Notes
Moisture and air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
Specifications

Specifications

o-Phenylenediamine
100°C to 103°C
256°C to 258°C
98%
MFCD00007721
UN1673
Air Sensitive
o-phenylenediamine, 1,2-phenylenediamine, 1,2-benzenediamine, 1,2-diaminobenzene, 2-aminoaniline, o-diaminobenzene, orthamine, o-benzenediamine, opda, ortho-phenylenediamine
GEYOCULIXLDCMW-UHFFFAOYSA-N
benzene-1,2-diamine
7243
108.14
95-54-5
1.27
136°C (277°F)
C6H8N2
25 g
606074
14,7284
Soluble in alcohol,chloroform,ether,slightly soluble in water; Soluble in hot water.
C1=CC=C(C(=C1)N)N
108.144
CHEBI:34043
98%

Chemical Identifiers

95-54-5
108.144
GEYOCULIXLDCMW-UHFFFAOYSA-N
7243
benzene-1,2-diamine
C6H8N2
MFCD00007721
o-phenylenediamine, 1,2-phenylenediamine, 1,2-benzenediamine, 1,2-diaminobenzene, 2-aminoaniline, o-diaminobenzene, orthamine, o-benzenediamine, opda, ortho-phenylenediamine
CHEBI:34043
C1=CC=C(C(=C1)N)N
Safety and Handling

Safety and Handling

GHS H Statement
H301-H341-H351-H312-H332-H319-H317
Toxic if swallowed.
Suspected of causing genetic defects.
Suspected of causing cancer.
Harmful in contact with skin.
Harmful if inhaled.
Causes serious eye irritation.
May cause an allergic skin reaction.

P201-P202-P261-P264b-P270-P271-P272-P280-P281-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P312-P330-P333+P313-P363-P501c

H301-H312+H332-H317-H319-H341-H351-H500

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: PHENYLENEDIAMINES

EINECSNumber : 202-430-6

RTECSNumber : SS7875000

TSCA : Yes

Recommended Storage : Ambient temperatures

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