Learn More
p-Benzoquinone, 98+%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A131620B
Description
p-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applicationsp-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.
Solubility
Soluble in water, ethanol, ether, methanol, benzene, acetone and ethyl acetate.
Notes
Light sensitive. Store in cool place. Incompatible and reacts violently with strong oxidizing agents.
Specifications
p-Benzoquinone | |
112°C to 115°C | |
∼180°C (sublimation) | |
≥98% | |
C6H4O2 | |
1000 g | |
773967 | |
14,8074 | |
Soluble in water,ethanol,ether,methanol,benzene,acetone and ethyl acetate. | |
C1=CC(=O)C=CC1=O | |
108.096 | |
CHEBI:16509 | |
≥98% |
106-51-4 | |
1.318 | |
77°C (171°F) | |
Pungent | |
MFCD00001591 | |
UN2587 | |
Light sensitive | |
p-benzoquinone, benzoquinone, quinone, 1,4-benzoquinone, p-quinone, chinone, 2,5-cyclohexadiene-1,4-dione, cyclohexadienedione, para-quinone, 1,4-benzoquine | |
AZQWKYJCGOJGHM-UHFFFAOYSA-N | |
cyclohexa-2,5-diene-1,4-dione | |
4650 | |
108.1 |
Chemical Identifiers
106-51-4 | |
108.096 | |
AZQWKYJCGOJGHM-UHFFFAOYSA-N | |
4650 | |
cyclohexa-2,5-diene-1,4-dione |
C6H4O2 | |
MFCD00001591 | |
p-benzoquinone, benzoquinone, quinone, 1,4-benzoquinone, p-quinone, chinone, 2,5-cyclohexadiene-1,4-dione, cyclohexadienedione, para-quinone, 1,4-benzoquine | |
CHEBI:16509 | |
C1=CC(=O)C=CC1=O |
Safety and Handling
GHS H Statement
H301-H331-H315-H319-H335
Toxic if swallowed.
Toxic if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P311-P330-P332+P313-P362-P501c
H301+H331-H315-H319-H335-H500
DOTInformation : Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: BENZOQUINONE
EINECSNumber : 203-405-2
RTECSNumber : DK2625000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only