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Phenyl chlorothionoformate, 98+%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals L0083806

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Catalog No. AAL0083806

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Description

Description

Phenyl chlorothionoformate has been used in stereo directed synthesis of optically active, (-)-mintlactone, synthesis of peptide α-thioesters having a variety of C-terminal amino acids, synthesis of scyllo-inositol derivatives, thionocarbonylation of unprotected thymine nucleosides, preparation of phenoxythiocarbonyl esters of protected ribonucleosides. It is also used as a reagent in the thionocarbonylation of unprotected thymine nucleosides. It forms phenoxythiocarbonyl esters of protected ribonucleosides which can be reduced by tributyltin hydride to deoxyribonucleosides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phenyl chlorothionoformate has been used in stereo directed synthesis of optically active, (-)-mintlactone, synthesis of peptide α-thioesters having a variety of C-terminal amino acids, synthesis of scyllo-inositol derivatives, thionocarbonylation of unprotected thymine nucleosides, preparation of phenoxythiocarbonyl esters of protected ribonucleosides. It is also used as a reagent in the thionocarbonylation of unprotected thymine nucleosides. It forms phenoxythiocarbonyl esters of protected ribonucleosides which can be reduced by tributyltin hydride to deoxyribonucleosides.

Solubility
Soluble in water.

Notes
Moisture, Heat Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.
Specifications

Specifications

Phenyl chlorothionoformate
1.248
81°C (177°F)
C7H5ClOS
MFCD00004920
UN3265
Moisture sensitive
Soluble in water.
ClC(=S)OC1=CC=CC=C1
172.63
172.63
1005-56-7
81°C to 83°C (6 mmHg)
Acrid
1.5804
5 g
774830
o-phenyl carbonochloridothioate, phenyl chlorothionoformate, o-phenyl chlorothioformate, phenyl chlorothioformate, phenyl thioxochloroformate, phenyl chlorothionocarbonate, phenoxythiocarbonyl chloride, chlorothioformic acid phenyl ester, o-phenyl chlorothionoformate, o-phenyl chlorothiocarbonate
KOSYAAIZOGNATQ-UHFFFAOYSA-N
O-phenyl chloromethanethioate
70498
≥98%

Chemical Identifiers

1005-56-7
172.63
KOSYAAIZOGNATQ-UHFFFAOYSA-N
70498
C7H5ClOS
MFCD00004920
o-phenyl carbonochloridothioate, phenyl chlorothionoformate, o-phenyl chlorothioformate, phenyl chlorothioformate, phenyl thioxochloroformate, phenyl chlorothionocarbonate, phenoxythiocarbonyl chloride, chlorothioformic acid phenyl ester, o-phenyl chlorothionoformate, o-phenyl chlorothiocarbonate
ClC(=S)OC1=CC=CC=C1
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Safety and Handling

Safety and Handling

GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.

P210-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H227-H314

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber : 213-736-4

TSCA : No

Recommended Storage : Keep cold; Store under Nitrogen

SDS
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RUO – Research Use Only