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Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals

Grignard reagent

Supplier:  Thermo Scientific Chemicals 087326AP

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Catalog No. AA87326AP


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Description

Description

Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Specifications

Phenylmagnesium bromide
Yellow to Brown
Ether-like
MFCD00000038
UN3399
phenylmagnesium bromide, grignard reagent, magnesium, bromophenyl, magnesium, bromophenyl, phenylmagnesiumbromide, bromo phenyl magnesium, bromo phenyl magnesium, phenyl magnesium bromide, bromomagnesiobenzene, phenyhnagnesium bromide, phenyhnagnesium bromide
ANRQGKOBLBYXFM-UHFFFAOYSA-M
magnesium;benzene;bromide
66852
3M in ether
100-58-3
1.14 g/mL
C6H5BrMg
500 mL
Air, light, and moisture sensitive; May form a Precipitate
Miscible with terahydrofuran.
Br[Mg]C1=CC=CC=C1
181.32
181.31
Liquid

Chemical Identifiers

100-58-3
181.32
ANRQGKOBLBYXFM-UHFFFAOYSA-M
66852
C6H5BrMg
MFCD00000038
phenylmagnesium bromide, grignard reagent, magnesium, bromophenyl, magnesium, bromophenyl, phenylmagnesiumbromide, bromo phenyl magnesium, bromo phenyl magnesium, phenyl magnesium bromide, bromomagnesiobenzene, phenyhnagnesium bromide, phenyhnagnesium bromide
Br[Mg]C1=CC=CC=C1
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Safety and Handling

Safety and Handling

GHS H Statement
H224-H261-H314-H336
Extremely flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.

P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H224-H314-H335-H336

DOTInformation : Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

SDS
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RUO – Research Use Only