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Pyridinium dichromate, 98%, Thermo Scientific Chemicals

Alfa Aesar Pyridinium dichromate, 98%, Quantity: 100g, Melting Point: ∼145 deg.C to 147 deg.C, Molecular Weight: 376.205, Percent Purity: 98%, CAS: 20039-37-6, DOT Information: Transport Hazard Class: 5.1; Packing Group: II; Proper Shipping Name: OXIDIZING SOLID, TOXIC, N.O.S.

Supplier:  Thermo Scientific Chemicals L1513236

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Catalog No. AAL1513236


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Description

Description

Pyridinium dichromate acts as a strong oxidizing agent used in the conversion of primary alcohols and secondary alcohols to aldehydes and ketones respectively. It plays an important role in the oxidation of unsaturated tertiary alcohols, silyl ethers, the carbon-boron bond, and oximes. Further, it is used in the conversion of acetals to esters and didehydroketones to enones in the presence of tert-butyl hydroperoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Pyridinium dichromate acts as a strong oxidizing agent used in the conversion of primary alcohols and secondary alcohols to aldehydes and ketones respectively. It plays an important role in the oxidation of unsaturated tertiary alcohols, silyl ethers, the carbon-boron bond, and oximes. Further, it is used in the conversion of acetals to esters and didehydroketones to enones in the presence of tert-butyl hydroperoxide.

Solubility
Soluble in water, dimethyl formamide, dimethyl sulfoxide and acetonitrile. Slightly soluble in dichloromethane, chloroform and acetone. Insoluble in hexane, ether and ethyl acetate.

Notes
Hygroscopic. Incompatible withorganic materials and powdered metals.
Specifications

Specifications

Pyridinium dichromate
∼145°C to 147°C
MFCD00013105
UN3087
pyridinium dichromate, cornforth reagent, pyridinium dichromate pdc, oxido-oxido dioxo chromio oxy-dioxochromium; pyridin-1-ium, pyridiniumdichromate, pyridinium-dichromate, dipyridinium dichromate, bis pyridium chromate, pyridiniumdichromate pdc, acmc-209f5g
LMYWWPCAXXPJFF-UHFFFAOYSA-P
oxido-(oxido(dioxo)chromio)oxy-dioxochromium;pyridin-1-ium
2724130
98%
20039-37-6
C10H12Cr2N2O7
500 g
Hygroscopic
Soluble in water,dimethyl formamide,dimethyl sulfoxide and acetonitrile. Slightly soluble in dichloromethane,chloroform and acetone. Insoluble in hexane,ether and ethyl acetate.
C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1.[O-][Cr](=O)(=O)O[Cr](=O)(=O)[O-]
376.205
376.21

Chemical Identifiers

20039-37-6
376.205
LMYWWPCAXXPJFF-UHFFFAOYSA-P
2724130
C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1.[O-][Cr](=O)(=O)O[Cr](=O)(=O)[O-]
C10H12Cr2N2O7
MFCD00013105
pyridinium dichromate, cornforth reagent, pyridinium dichromate pdc, oxido-oxido dioxo chromio oxy-dioxochromium; pyridin-1-ium, pyridiniumdichromate, pyridinium-dichromate, dipyridinium dichromate, bis pyridium chromate, pyridiniumdichromate pdc, acmc-209f5g
oxido-(oxido(dioxo)chromio)oxy-dioxochromium;pyridin-1-ium
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Safety and Handling

Safety and Handling

GHS H Statement
H351-H317
Suspected of causing cancer.
May cause an allergic skin reaction.

P201-P202-P210-P220-P221-P240-P241-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H228-H272-H314-H335-H350i-H373

DOTInformation : Transport Hazard Class: 5.1; Packing Group: II; Proper Shipping Name: OXIDIZING SOLID, TOXIC, N.O.S.

EINECSNumber : 243-478-8

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

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