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Sodium bis(trimethylsilyl)amide, 2M soln. in THF, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals L13352AP
Description
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsSodium bis(trimethylsilyl)amide is a strong base used in organic synthesis for deprotonation reactions and base catalyzed reaction. It is also used to enhance the polymerization of pheneylacetylene in conjunction with rhodium(I) catalysis. It is involved in the generation of enolates, Wittig reagents and carbenes.
Solubility
Miscible with benzene and toluene.
Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, strong oxidizing agents and oxygen. Dry residue is explosive.
Specifications
| Sodium bis(trimethylsilyl)amide | |
| 500 mL | |
| MFCD00009835 | |
| 3629917 | |
| sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt | |
| WRIKHQLVHPKCJU-UHFFFAOYSA-N | |
| sodium;bis(trimethylsilyl)azanide | |
| 2724254 | |
| 2M soln. in THF | |
| 0.92 |
| 1070-89-9 | |
| C6H18NNaSi2 | |
| UN2924 | |
| −17°C (1°F) | |
| Miscible with benzene and toluene. | |
| C[Si](C)(C)[N-][Si](C)(C)C.[Na+] | |
| 183.377 | |
| 183.38 | |
| Moisture sensitive; May form a precipitate |
Chemical Identifiers
| 1070-89-9 | |
| 183.377 | |
| WRIKHQLVHPKCJU-UHFFFAOYSA-N | |
| 2724254 | |
| C[Si](C)(C)[N-][Si](C)(C)C.[Na+] |
| C6H18NNaSi2 | |
| MFCD00009835 | |
| sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt | |
| sodium;bis(trimethylsilyl)azanide |
Safety and Handling
GHS H Statement
H225-H314-H351-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.
P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
H225-H302-H314-H335-H336-H341-H351
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber : 213-983-8
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only