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TEMPO, free radical, 98+%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1273306

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Catalog No. AAA1273306


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Description

Description

TEMPO is used as a catalyst in organic synthesis and for the oxidation of primary alcohols to aldehydes. It finds use in the chemical industry for conversion of bisnoralcohol (a steroid) to bisnoraldehyde. It acts as a free radical scavenger, as a mediator in controlled radical polymerization and as a structural probe in electron spin resonance spectroscopy. Further, it is involved in the preparation of (S)-(+)-2-methylbutanal from (S)-(-)-2-methyl-1-butanol.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
TEMPO is used as a catalyst in organic synthesis and for the oxidation of primary alcohols to aldehydes. It finds use in the chemical industry for conversion of bisnoralcohol (a steroid) to bisnoraldehyde. It acts as a free radical scavenger, as a mediator in controlled radical polymerization and as a structural probe in electron spin resonance spectroscopy. Further, it is involved in the preparation of (S)-(+)-2-methylbutanal from (S)-(-)-2-methyl-1-butanol.

Solubility
Soluble in all organic solvents. Insoluble in water.

Notes
Store in a cool place. Incompatible withstrong oxidizing agents and strong acids.
Specifications

Specifications

TEMPO
2564-83-2
193°C (decomposition)
C9H18NO
5 g
1422418
2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical
QYTDEUPAUMOIOP-UHFFFAOYSA-N
(2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl
156.25
free radical
31°C to 40°C
67°C (152°F)
MFCD00009599
UN3263
14,9140
Soluble in all organic solvents. Insoluble in water.
CC1(C)CCCC(C)(C)N1[O]
156.25
≥98%

Chemical Identifiers

2564-83-2
156.25
QYTDEUPAUMOIOP-UHFFFAOYSA-N
(2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl
C9H18NO
MFCD00009599
2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical
CC1(C)CCCC(C)(C)N1[O]
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Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.

EINECSNumber : 219-888-8

RTECSNumber : TN8991900

TSCA : Yes

Recommended Storage : Keep cold

SDS
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