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tert-Butyl hydroperoxide, 70% aq. soln., Thermo Scientific Chemicals
$61.92 - $524.11
Chemical Identifiers
| CAS | 75-91-2 |
|---|---|
| Molecular Formula | C4H10O2 |
| Molecular Weight (g/mol) | 90.122 |
| MDL Number | MFCD00002130 |
| InChI Key | CIHOLLKRGTVIJN-UHFFFAOYSA-N |
| Synonym | tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid |
| PubChem CID | 6410 |
| ChEBI | CHEBI:64090 |
| IUPAC Name | 2-hydroperoxy-2-methylpropane |
| SMILES | CC(C)(C)OO |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA13926AE
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Thermo Scientific Chemicals
A13926AE |
100 mL |
Each for $61.92
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AAA13926AP
|
Thermo Scientific Chemicals
A13926AP |
500 mL |
Each for $124.73
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AAA139260F
|
Thermo Scientific Chemicals
A139260F |
2500 mL |
Each for $524.11
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Description
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applicationstert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.
Solubility
Miscible with water and diethyl ether.
Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
Chemical Identifiers
| 75-91-2 | |
| 90.122 | |
| CIHOLLKRGTVIJN-UHFFFAOYSA-N | |
| 6410 | |
| 2-hydroperoxy-2-methylpropane |
| C4H10O2 | |
| MFCD00002130 | |
| tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid | |
| CHEBI:64090 | |
| CC(C)(C)OO |
Specifications
| 75-91-2 | |
| 0.937 | |
| 43°C (109°F) | |
| C4H10O2 | |
| (CH3)3COOH | |
| 100 mL | |
| 1098280 | |
| tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid | |
| CIHOLLKRGTVIJN-UHFFFAOYSA-N | |
| 2-hydroperoxy-2-methylpropane | |
| 6410 | |
| 90.12 | |
| tert-Butyl hydroperoxide |
| -3°C | |
| 96°C (decomposition) | |
| 70% Aqueous Solution | |
| 1.387 | |
| MFCD00002130 | |
| UN3109 | |
| 14,1570 | |
| Miscible with water and diethyl ether. | |
| CC(C)(C)OO | |
| 90.122 | |
| CHEBI:64090 | |
| 70% aq. soln. |
Safety and Handling
GHS H Statement
H300-H310-H330-H314-H226-H242
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Flammable liquid and vapour.
Heating may cause a fire.
P201-P202-P210-P220-P233-P234-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P272-P280g-P281-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P37
H226-H242-H302-H311-H314-H317-H330-H335-H341
DOTInformation : Hazard Class: 5.2
EINECSNumber : 200-915-7
RTECSNumber : EQ4900000
TSCA : Yes
Recommended Storage : Keep cold
RUO – Research Use Only