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Trimethyl phosphonoacetate, 98%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A1330136
Description
Trimethyl phosphonoacetate is used in the preparation of sarin A by intramolecular Mannich-type reactions. It is involved in the Horner-Wadsworth-Emmons olefination with aldehydes and ketones to give acrylic esters. It is also involved in oxa-Michael reactions, prenylation of oxindoles and heterocyclization reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTrimethyl phosphonoacetate is used in the preparation of sarin A by intramolecular Mannich-type reactions. It is involved in the Horner-Wadsworth-Emmons olefination with aldehydes and ketones to give acrylic esters. It is also involved in oxa-Michael reactions, prenylation of oxindoles and heterocyclization reactions.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
Specifications
| Trimethyl phosphonoacetate | |
| 1.263 | |
| 70°C (158°F) | |
| 1.437 | |
| 500 g | |
| trimethyl phosphonoacetate, methyl 2-dimethoxyphosphoryl acetate, trimethyl phosphonacetate, trimethylacetyl phosphate, acetic acid, dimethoxyphosphinyl-, methyl ester, methyl-dimethoxyphosphoryl acetat, trimethyl phosphoroacetate, phosphonoacetic acid trimethyl ester, methyl dimethylphosphonoacetate, methyl dimethoxyphosphoryl acetate | |
| SIGOIUCRXKUEIG-UHFFFAOYSA-N | |
| methyl 2-dimethoxyphosphorylacetate | |
| 80029 | |
| 98% |
| 5927-18-4 | |
| 119°C to 120°C (1 mmHg) | |
| C5H11O5P | |
| MFCD00008452 | |
| 1865177 | |
| Slightly miscible with water. | |
| COC(=O)CP(=O)(OC)OC | |
| 182.112 | |
| 182.11 |
Chemical Identifiers
| 5927-18-4 | |
| 182.112 | |
| SIGOIUCRXKUEIG-UHFFFAOYSA-N | |
| 80029 | |
| COC(=O)CP(=O)(OC)OC |
| C5H11O5P | |
| MFCD00008452 | |
| trimethyl phosphonoacetate, methyl 2-dimethoxyphosphoryl acetate, trimethyl phosphonacetate, trimethylacetyl phosphate, acetic acid, dimethoxyphosphinyl-, methyl ester, methyl-dimethoxyphosphoryl acetat, trimethyl phosphoroacetate, phosphonoacetic acid trimethyl ester, methyl dimethylphosphonoacetate, methyl dimethoxyphosphoryl acetate | |
| methyl 2-dimethoxyphosphorylacetate |
Safety and Handling
GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.
GHS P Statement
P210-P261-P280-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Warning
EINECSNumber : 227-663-0
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only