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1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, 97%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals L0693114

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Catalog No. AAL0693114


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Description

Description

1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.

Solubility
Hydrolyzes in water.

Notes
Moisture Sensitive. Incompatible materials are Strong oxidizing agents and Strong acids. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specifications

Specifications

35°C to 36°C (15mmHg)
31469-15-5
C8H18O2Si
UN1993
30°C (86°F)
Hydrolyzes in water.
COC(O[Si](C)(C)C)=C(C)C
174.32
174.32
1.415
0.858
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene
25 g
MFCD00010232
1362893
1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane
JNOGVQJEBGEKMG-UHFFFAOYSA-N
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
552336
97%
Moisture sensitive

Chemical Identifiers

31469-15-5
174.32
JNOGVQJEBGEKMG-UHFFFAOYSA-N
552336
COC(O[Si](C)(C)C)=C(C)C
C8H18O2Si
MFCD00010232
1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
Safety and Handling

Safety and Handling

GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

H226-H315-H319-H335

DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.

EINECSNumber : 000-000-0

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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