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1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, 97%, Thermo Scientific Chemicals
$136.12 - $497.74
Chemical Identifiers
| CAS | 31469-15-5 |
|---|---|
| Molecular Formula | C8H18O2Si |
| Molecular Weight (g/mol) | 174.32 |
| MDL Number | MFCD00010232 |
| InChI Key | JNOGVQJEBGEKMG-UHFFFAOYSA-N |
| Synonym | 1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane |
| PubChem CID | 552336 |
| IUPAC Name | (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane |
| SMILES | COC(O[Si](C)(C)C)=C(C)C |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL0693106
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Thermo Scientific Chemicals
L0693106 |
5 g |
Each for $136.12
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AAL0693114
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Thermo Scientific Chemicals
L0693114 |
25 g |
Each for $497.74
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Description
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.
Solubility
Hydrolyzes in water.
Notes
Moisture Sensitive. Incompatible materials are Strong oxidizing agents and Strong acids. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Chemical Identifiers
| 31469-15-5 | |
| 174.32 | |
| JNOGVQJEBGEKMG-UHFFFAOYSA-N | |
| 552336 | |
| COC(O[Si](C)(C)C)=C(C)C |
| C8H18O2Si | |
| MFCD00010232 | |
| 1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane | |
| (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane |
Specifications
| 35°C to 36°C (15mmHg) | |
| 5 g | |
| MFCD00010232 | |
| 1362893 | |
| 1-methoxy-2-methyl-1-trimethylsiloxy propene, methyl trimethylsilyl dimethylketene acetal, dimethylketene methyl trimethylsilyl acetal, 1-methoxy-2-methylprop-1-en-1-yl oxy trimethylsilane, silane, 1-methoxy-2-methyl-1-propenyl oxy trimethyl, 1-methoxy-1-trimethylsiloxy-2-methyl-1-propene, dimethylketene methyltrimethylsilylacetal, 1-methoxy-1-trimethylsilyloxy-2-methylpropene, 1-methoxy-2-methyl-1-propenyloxy trimethylsilane, 1-methoxy-2-methylprop-1-enoxy-trimethylsilane | |
| JNOGVQJEBGEKMG-UHFFFAOYSA-N | |
| (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane | |
| 552336 | |
| 97% | |
| Moisture sensitive | |
| 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene |
| 31469-15-5 | |
| C8H18O2Si | |
| UN1993 | |
| 30°C (86°F) | |
| Hydrolyzes in water. | |
| COC(O[Si](C)(C)C)=C(C)C | |
| 174.32 | |
| 174.32 | |
| 1.415 | |
| 0.858 |
Safety and Handling
GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H226-H315-H319-H335
DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
EINECSNumber : 000-000-0
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only