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Hydrogen fluoride pyridine complex, ca 70% HF, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals L1711722
Description
Hydrogen fluoride pyridine complex is used to prepare beta-fluoroamines via reaction with amino alcohols. As a fluorinating agent, is involved in the fluorination of 2,2-diary-1,3-dithiolanes. It is associated with nitrosonium tetrafluorborate to prepare gem-difluorides by reacting with ketoximes. It is also used to convert secondary and tertiary alcohols into their respective alkyl fluorides.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsHydrogen fluoride pyridine complex is used to prepare beta-fluoroamines via reaction with amino alcohols. As a fluorinating agent, is involved in the fluorination of 2,2-diary-1,3-dithiolanes. It is associated with nitrosonium tetrafluorborate to prepare gem-difluorides by reacting with ketoximes. It is also used to convert secondary and tertiary alcohols into their respective alkyl fluorides.
Notes
Moisture sensitive. Store in cool place. Incompatible with strong bases, alkali metals, strong oxidizing agents, metals and strong acids. It reacts violently with water.
Specifications
Hydrogen fluoride pyridine complex | |
1.1 | |
≈70% HF | |
MFCD00012436 | |
UN1790 | |
Moisture sensitive | |
pyridine hydrofluoride, hydrogen fluoride-pyridine, olah's reagent, pyridinium fluoride, hydrogen fluoride pyridine complex, hydrogen fluoride pyridine, hf-pyridine, pyridine, hydrofluoride 1:1, pyridinium poly hydrogen fluoride, hydrogen fluoride/pyridine | |
C1=CC=NC=C1.F | |
99.108 |
62778-11-4 | |
50°C (1 mmHg) | |
C5H6FN | |
100 g | |
4750151 | |
14,6821 | |
GRJJQCWNZGRKAU-UHFFFAOYSA-N | |
pyridine;hydrofluoride | |
64774 |
Chemical Identifiers
62778-11-4 | |
99.108 | |
GRJJQCWNZGRKAU-UHFFFAOYSA-N | |
64774 | |
C1=CC=NC=C1.F |
C5H6FN | |
MFCD00012436 | |
pyridine hydrofluoride, hydrogen fluoride-pyridine, olah's reagent, pyridinium fluoride, hydrogen fluoride pyridine complex, hydrogen fluoride pyridine, hf-pyridine, pyridine, hydrofluoride 1:1, pyridinium poly hydrogen fluoride, hydrogen fluoride/pyridine | |
pyridine;hydrofluoride |
Safety and Handling
GHS H Statement
H300-H310-H330-H314-H318
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P262-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c
H300+H310+H330-H314-H335
DOTInformation : Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: HYDROFLUORIC ACID
TSCA : No
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only