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Hydrogen fluoride pyridine complex, ca 70% HF, Thermo Scientific Chemicals

$103.49 - $198.81

Chemical Identifiers

CAS 62778-11-4
Molecular Formula C5H6FN
Molecular Weight (g/mol) 99.108
MDL Number MFCD00012436
InChI Key GRJJQCWNZGRKAU-UHFFFAOYSA-N
Synonym pyridine hydrofluoride, hydrogen fluoride-pyridine, olah's reagent, pyridinium fluoride, hydrogen fluoride pyridine complex, hydrogen fluoride pyridine, hf-pyridine, pyridine, hydrofluoride 1:1, pyridinium poly hydrogen fluoride, hydrogen fluoride/pyridine
PubChem CID 64774
IUPAC Name pyridine;hydrofluoride
SMILES C1=CC=NC=C1.F
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Products 2
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL1711714
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Thermo Scientific Chemicals
L1711714
25 g
Each for $103.49
 
AAL1711722
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Thermo Scientific Chemicals
L1711722
100 g
Each for $198.81
 
Description

Description

Hydrogen fluoride pyridine complex is used to prepare beta-fluoroamines via reaction with amino alcohols. As a fluorinating agent, is involved in the fluorination of 2,2-diary-1,3-dithiolanes. It is associated with nitrosonium tetrafluorborate to prepare gem-difluorides by reacting with ketoximes. It is also used to convert secondary and tertiary alcohols into their respective alkyl fluorides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hydrogen fluoride pyridine complex is used to prepare beta-fluoroamines via reaction with amino alcohols. As a fluorinating agent, is involved in the fluorination of 2,2-diary-1,3-dithiolanes. It is associated with nitrosonium tetrafluorborate to prepare gem-difluorides by reacting with ketoximes. It is also used to convert secondary and tertiary alcohols into their respective alkyl fluorides.

Notes
Moisture sensitive. Store in cool place. Incompatible with strong bases, alkali metals, strong oxidizing agents, metals and strong acids. It reacts violently with water.
Specifications

Chemical Identifiers

62778-11-4
99.108
GRJJQCWNZGRKAU-UHFFFAOYSA-N
64774
C1=CC=NC=C1.F
C5H6FN
MFCD00012436
pyridine hydrofluoride, hydrogen fluoride-pyridine, olah's reagent, pyridinium fluoride, hydrogen fluoride pyridine complex, hydrogen fluoride pyridine, hf-pyridine, pyridine, hydrofluoride 1:1, pyridinium poly hydrogen fluoride, hydrogen fluoride/pyridine
pyridine;hydrofluoride

Specifications

62778-11-4
50°C (1 mmHg)
MFCD00012436
UN1790
Moisture sensitive
pyridine hydrofluoride, hydrogen fluoride-pyridine, olah's reagent, pyridinium fluoride, hydrogen fluoride pyridine complex, hydrogen fluoride pyridine, hf-pyridine, pyridine, hydrofluoride 1:1, pyridinium poly hydrogen fluoride, hydrogen fluoride/pyridine
C1=CC=NC=C1.F
99.108
Hydrogen fluoride pyridine complex
1.1
C5H6FN
25 g
4750151
14,6821
GRJJQCWNZGRKAU-UHFFFAOYSA-N
pyridine;hydrofluoride
64774
≈70% HF
Safety and Handling

Safety and Handling

GHS H Statement
H300-H310-H330-H314-H318
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P262-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

H300+H310+H330-H314-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: HYDROFLUORIC ACID

TSCA : No

Recommended Storage : Keep cold; Store under Nitrogen

SDS
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RUO – Research Use Only