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tert-Butyl nitrite, tech. 90%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals L1613522
Description
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applicationstert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.
Solubility
Miscible with diethyl ether, chloroform, alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.
Notes
Light sensitive. Store in cool place. Incompatible with strong reducing agents, powdered metals and strong acids.
Specifications
tert-Butyl nitrite | |
0.867 | |
−23°C (−9°F) | |
C4H9NO2 | |
MFCD00002055 | |
UN2351 | |
14,1583 | |
Miscible with diethyl ether,chloroform,alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol. | |
CC(C)(C)ON=O | |
103.121 | |
103.12 | |
Technical |
540-80-7 | |
61°C to 63°C | |
Sweet | |
1.369 | |
100 g | |
1209339 | |
t-butyl nitrite, 1,1-dimethylethyl nitrite, tert-butylnitrite, nitrous acid, 1,1-dimethylethyl ester, unii-4780h7u8lu, ccris 2098, alpha,alpha-dimethylethyl nitrite, nitrous acid, t-butyl ester, 2-methyl-2-propylnitrit, ch3 3cono | |
IOGXOCVLYRDXLW-UHFFFAOYSA-N | |
tert-butyl nitrite | |
10906 | |
90% |
Chemical Identifiers
540-80-7 | |
103.121 | |
IOGXOCVLYRDXLW-UHFFFAOYSA-N | |
10906 | |
CC(C)(C)ON=O |
C4H9NO2 | |
MFCD00002055 | |
t-butyl nitrite, 1,1-dimethylethyl nitrite, tert-butylnitrite, nitrous acid, 1,1-dimethylethyl ester, unii-4780h7u8lu, ccris 2098, alpha,alpha-dimethylethyl nitrite, nitrous acid, t-butyl ester, 2-methyl-2-propylnitrit, ch3 3cono | |
tert-butyl nitrite |
Safety and Handling
GHS H Statement
H225-H302-H332
Highly flammable liquid and vapor.
Harmful if swallowed.
Harmful if inhaled.
P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P312-P330-P370+P378q-P501c
H225-H302+H332
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: BUTYL NITRITES
EINECSNumber : 208-757-0
RTECSNumber : RA0802000
TSCA : No
Recommended Storage : Keep cold
RUO – Research Use Only