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Triisopropylsilyl trifluoromethanesulfonate, 97%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals B2112722

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Catalog No. AAB2112722



Description

Description

Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.

Solubility
Miscible with chloroform and ethyl acetate.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents. Hydrolyzes in water.
Specifications

Specifications

Triisopropylsilyl trifluoromethanesulfonate
1.136
100°C (212°F)
1.415
100 g
3591541
triisopropylsilyl trifluoromethanesulfonate, triisopropylsilyl triflate, triisopropylsilyltrifluoromethanesulfonate, trifluoromethanesulfonic acid triisopropylsilyl ester, tips-otf, tips triflate, wacker silane ip3-triflate, triisopropylsilyl trifluoromethanesulphonate, triisopropylsilyl-trifluoromethanesulfonate, methanesulfonic acid, trifluoro-, tris 1-methylethyl silyl ester
LHJCZOXMCGQVDQ-UHFFFAOYSA-N
tri(propan-2-yl)silyl trifluoromethanesulfonate
2724529
97%
80522-42-5
45°C to 46°C (0.03 mmHg)
C10H21F3O3SSi
MFCD00009913
UN3265
Moisture sensitive
Miscible with chloroform and ethyl acetate.
CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F
306.415
306.42

Chemical Identifiers

80522-42-5
306.415
LHJCZOXMCGQVDQ-UHFFFAOYSA-N
2724529
CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F
C10H21F3O3SSi
MFCD00009913
triisopropylsilyl trifluoromethanesulfonate, triisopropylsilyl triflate, triisopropylsilyltrifluoromethanesulfonate, trifluoromethanesulfonic acid triisopropylsilyl ester, tips-otf, tips triflate, wacker silane ip3-triflate, triisopropylsilyl trifluoromethanesulphonate, triisopropylsilyl-trifluoromethanesulfonate, methanesulfonic acid, trifluoro-, tris 1-methylethyl silyl ester
tri(propan-2-yl)silyl trifluoromethanesulfonate
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber : 000-000-0

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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