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Triisopropylsilyl trifluoromethanesulfonate, 97%, Thermo Scientific Chemicals
$83.16 - $816.03
Chemical Identifiers
| CAS | 80522-42-5 |
|---|---|
| Molecular Formula | C10H21F3O3SSi |
| Molecular Weight (g/mol) | 306.415 |
| MDL Number | MFCD00009913 |
| InChI Key | LHJCZOXMCGQVDQ-UHFFFAOYSA-N |
| Synonym | triisopropylsilyl trifluoromethanesulfonate, triisopropylsilyl triflate, triisopropylsilyltrifluoromethanesulfonate, trifluoromethanesulfonic acid triisopropylsilyl ester, tips-otf, tips triflate, wacker silane ip3-triflate, triisopropylsilyl trifluoromethanesulphonate, triisopropylsilyl-trifluoromethanesulfonate, methanesulfonic acid, trifluoro-, tris 1-methylethyl silyl ester |
| PubChem CID | 2724529 |
| IUPAC Name | tri(propan-2-yl)silyl trifluoromethanesulfonate |
| SMILES | CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAB2112706
|
Thermo Scientific Chemicals
B2112706 |
5 g |
Each for $83.16
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AAB2112714
|
Thermo Scientific Chemicals
B2112714 |
25 g |
Each for $255.81
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AAB2112722
|
Thermo Scientific Chemicals
B2112722 |
100 g |
Each for $816.03
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Description
Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.
Solubility
Miscible with chloroform and ethyl acetate.
Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents. Hydrolyzes in water.
Chemical Identifiers
| 80522-42-5 | |
| 306.415 | |
| LHJCZOXMCGQVDQ-UHFFFAOYSA-N | |
| 2724529 | |
| CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F |
| C10H21F3O3SSi | |
| MFCD00009913 | |
| triisopropylsilyl trifluoromethanesulfonate, triisopropylsilyl triflate, triisopropylsilyltrifluoromethanesulfonate, trifluoromethanesulfonic acid triisopropylsilyl ester, tips-otf, tips triflate, wacker silane ip3-triflate, triisopropylsilyl trifluoromethanesulphonate, triisopropylsilyl-trifluoromethanesulfonate, methanesulfonic acid, trifluoro-, tris 1-methylethyl silyl ester | |
| tri(propan-2-yl)silyl trifluoromethanesulfonate |
Specifications
| 80522-42-5 | |
| 45°C to 46°C (0.03 mmHg) | |
| C10H21F3O3SSi | |
| MFCD00009913 | |
| UN3265 | |
| Moisture sensitive | |
| Miscible with chloroform and ethyl acetate. | |
| CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F | |
| 306.415 | |
| 306.42 | |
| Triisopropylsilyl trifluoromethanesulfonate |
| 1.136 | |
| 100°C (212°F) | |
| 1.415 | |
| 5 g | |
| 3591541 | |
| triisopropylsilyl trifluoromethanesulfonate, triisopropylsilyl triflate, triisopropylsilyltrifluoromethanesulfonate, trifluoromethanesulfonic acid triisopropylsilyl ester, tips-otf, tips triflate, wacker silane ip3-triflate, triisopropylsilyl trifluoromethanesulphonate, triisopropylsilyl-trifluoromethanesulfonate, methanesulfonic acid, trifluoro-, tris 1-methylethyl silyl ester | |
| LHJCZOXMCGQVDQ-UHFFFAOYSA-N | |
| tri(propan-2-yl)silyl trifluoromethanesulfonate | |
| 2724529 | |
| 97% |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 000-000-0
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only